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Punktid
Aim
Determination of total and carbonate hardness of tap water using titration technique.
Eliminating total hardness with a Na+ ion- exchange softener.
Reagents
0.1 M hydrochloric acid, 0,025 M and 0,005M trilon-B solution , buffer solution (NH4Cl + NH3∙H2O), indicators methyl red (mr) or methyl orange (mo) and chromogen black ET-00.
Apparatus
Conical flasks (250 ml, 500 ml), measuring cylinder (25 cm3), burette (25 cm3), pipettes (100 cm3).
Experimental Procedure
A Determination of carbonate hardness
  • Rinse the 100 cm3 pipette 2...3 times with a small amount of the test water. Wash the conical flask with distilled water. Pipette 100 cm3 of the test water and transfer it into the conical flask, add 3...4 drops of indicator mo or mr.
  • Prepare the burette – remove any air bubbles from the nozzle and fill with 0.1 M hydrochloric acid till zero (The lower meniscus has to coincide with the scales 0-notation).
  • Titrate with a 0.1 M hydrochloric acid solution, while swirling the water in the flask with intense circular movements. At the equivalence point the color of the water will change from yellow to orange red. It is important to end the titration process precisely (one drop precision ) when the red color stays unchanged when adding the last drop. Read from the burette the consumed volume of hydrochloric acid for titration with a 0.05 cm3 precision.
  • Wash the conical flask carefully with distilled water and repeat the titration with a new aliquote of water. Repeat the titration process until the consumed amounts of at least three readings of HCl volume do not differ more than 0.10...0.15 cm3.
  • Put the data obtained from titration into the table and calculate the average volume of HCl solution used (cm3).
    B Determination of total hardness
  • Pipette 100 cm3 of the test water into a conical flask which has been washed with distilled water, add ~5 cm3 of buffer solution ( measure it with a 25 cm3 measuring cylinder), add a pinch (~0,1 g) of the indicator ET-00. The color of solution will change to purple .
  • Prepare the burette with 0,025 M trilon-B solution and titrate water while constantly swirling until the color of solution changes to blue . Titrate carefully further until the last added drop will not change the blue color of the solution.
  • Repeat the titration until at least three consumed volumes of trilon-B do not differ more than 0.10...0.15 cm3.
  • Put the data obtained from titration into the table and calculate the average volume of the trilon B solution consumed (cm3).
    C Water softening and determination of the residual total hardness
    Pour water through the sodium cationite filter and collect the softened water into a beaker or a conical flask. Determine total hardness of the softened water and assess efficiency of the filter.
  • Pipette 100 cm3 of the softened water into the clean conical flask (NB! Rinse pipette couple of times with a small amount of softened water), add ~5 cm3 of a buffer solution and a pinch (~0,1 g) of indicator ET-00.
  • Prepare the burette with more dilute 0,005 M trilon-B solution and titrate water as in part B of lab until the blue color appears .
  • Calculate the residual total hardness as in part B.
    Results
    A:
    ml of 0,005M trilone B solution
  • 2,50
  • 2,45
  • 2,45
    Avarage: 2,47ml
    B:
    ml of 0,025M trilone B solution
  • 6,85
  • 6,90
  • 6,85
    Avarage: 6,87ml
    C:
    ml of 0,005M trilone B solution is 0
    Practical calculation
    A:
    Based on the best coinciding titration results average, calculating carbonate hardness according to the following formula:
    B:
    Based on the titration results average calculate the total hardness according to the following formula:
    C:
    Based on the titration results average calculate the total hardness according to the following formula:

    Conclution


    Softening with ion changer is helpful. Water hardness dissappared almost totally.
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    Autor Lennu123 Õppematerjali autor
    Determination of total and carbonate hardness of tap water using titration technique.
    Eliminating total hardness with a Na ion-exchange softener.

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